Activation of metal-bound η5-C5Me5groups to Diels–Alder addition of 3O2 and other dienophiles
Literature Information
Publication Date
2009-01-27
DOI
10.1039/B818537A
Impact Factor
6.222
Authors
Neil M. Boag, K. Mohan Rao
View Original
Abstract
Pt(η5-C5Me5)(PR3)I (PR3 = PPh3, PPhCy2, PPhMetBu) reacts with 3O2 to form the metal-bound endoperoxide Pt(η1,η2-C5Me5O2)(PR3)I; analogous reactions of Pt(η5-C5Me5)(PPh3)I with a variety of other dienophiles to form Pt(η1,η2-C5Me5CH2CHR)(PPh3)I (R = C(O)H, CO2Me, C(O)Et) in which the metal is anti to the incoming dienophile are indicative of direct Diels–Alder addition to the η5-C5Me5 ring.
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Source Journal
Chemical Communications
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4.7%
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Recommended Compounds
4-(4-Chloro-2-methoxyphenyl)-3-fluorobenzoic acid
CAS Number:
1261970-23-3
Molecular Formula:
C14H10ClFO3
4-(3-((4-Chloro-6-methoxyquinolin-7-yl)oxy)propyl)morpholine
CAS Number:
205448-32-4
Molecular Formula:
C17H21ClN2O3
4-(4-Methoxyphenyl)-5-methyl-1,3-thiazol-2-amine
CAS Number:
105512-88-7
Molecular Formula:
C11H12N2OS
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