Effect of adsorbate mass on an Eley–Rideal reaction. Reactive scattering of Cs+ from noble gases and N2 adsorbed on Ru(0001) surfaces at hyperthermal energy

Literature Information

Publication Date 2009-02-06
DOI 10.1039/B815764B
Impact Factor 3.676
Authors

Chang-Woo Lee, Poong-Ryul Lee, Rob J. W. E. Lahaye, Heon Kang


View Original

Abstract

The effect of the adsorbate mass on an Eley–Rideal (ER) reaction is examined for the reactive ion scattering (RIS) of Cs+ from physisorbed adsorbates (Ar, Kr, Xe and N2) on a Ru(0001) surface at hyperthermal energy (10–60 eV). The measurement of the RIS cross-section, or the efficiency for ER-type abstraction of surface adsorbates, reveals an inverse proportionality between the square root of the cross-section and the mass of the noble gases. This relationship is explained by the inertia effect which can determine the probability of successful abstraction events of the adsorbates. The result confirms a theoretical prediction that the inertia effect is important for the dynamics of an ER reaction in the hyperthermal energy regime.

Related Literature

Nickel(ii)/Lewis acid catalysed olefin hydroamination and hydroarylation under mild conditions

Kaiwen Li, Hongwu Jiang, Shuangfeng Dong, Shuang-Long Li, Zhuqi Chen, Guochuan Yin

2023-12-20 Paper

DOI: 10.1039/D3OB01770B

Photoredox radical cyclization reaction of o-vinylaryl isocyanides with acyl chlorides to access 2,4-disubstituted quinolines

Peng-Fei Huang, Jia-Le Fu, Jia-Jing Huang, Bi-Quan Xiong, Ke-Wen Tang, Yu Liu

2023-12-18 Paper

DOI: 10.1039/D3OB01915B

Carbenes from cyclopropanated aromatics

Alexander D. Roth, Dasan M. Thamattoor

2023-11-16 Review Article

DOI: 10.1039/D3OB01525D

Proline-catalyzed synthesis of α-substituted (E)-α,β-unsaturated aldehydes from epoxides

Ajay Sharma, Satyendra Kumar Pandey

2023-11-23 Communication

DOI: 10.1039/D3OB01750H

Visible-light-induced decarboxylative cascade cyclization of acryloylbenzamides with N-hydroxyphthalimide esters via EDA complexes

Qing Li, Zhi-Qiang Zhu, Wen-Yi Zhang, Zhang-Gao Le, Zong-Bo Xie

2024-01-04 Communication

DOI: 10.1039/D3OB01970E

Front cover

2024-01-17 Cover

DOI: 10.1039/D4OB90007C

Multigram-scale chemoenzymatic synthesis of diverse aminopolycarboxylic acids as potential metallo-β-lactamase inhibitors

Mohammad Faizan Bhat, Alejandro Prats Luján, Mohammad Saifuddin, Peter Fodran, Gerrit J. Poelarends

2023-12-12 Communication

DOI: 10.1039/D3OB01405C

You might also like

Compound Q&A

What regulatory guidelines apply to 4-Amino-3-bromophenol (CAS: 74440-80-5)?

4-Amino-3-bromophenol (CAS: 74440-80-5) falls under the classification of a haza...

74440-80-54-Amino-3-bromopheno...
Compound Q&A

How should (17beta)-3-Oxoestr-4-en-17-yl acetate (CAS: 1425-10-1) be stored?

(17beta)-3-Oxoestr-4-en-17-yl acetate should be stored in a cool, dry place away...

1425-10-1(17beta)-3-Oxoestr-4...
Compound Q&A

What are the physical and chemical properties of 2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0)?

2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0) is a colo...

76505-71-02-[(2,2-Diethoxyethy...
Compound Q&A

What is the market or research trend for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-amine?

The market and research for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-ami...

6736-58-91-(beta-D-Ribofurano...
Compound Q&A

How should waste containing Conjugated Estrogen (CAS: 12126-59-9) be handled?

Waste containing Conjugated Estrogen (CAS: 12126-59-9) should be collected and d...

12126-59-9Conjugated Estrogen
Compound Q&A

What is the market or research trend for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate?

The market for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate (CAS...

88738-78-7Bis(2,2,2-trifluoroe...
Compound Q&A

Are there alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9) in synthesis?

There are several alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9)...

57499-59-93,4'-Di-O-methylella...
Compound Q&A

What regulatory guidelines apply to 2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0)?

2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0) is regulated under the Gl...

59047-70-02-Chloro-N,N-dimethy...
Compound Q&A

What is cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8)?

Cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8) is a complex inorganic comp...

13597-19-8cerium(3+);oxygen(2-...
Compound Q&A

Is 7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) safe?

7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) is generally considered safe whe...

1203579-27-47-Chloro-1-iodoisoqu...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.