Rotational spectrum and equilibrium structure of silanethione, H2SiS

Literature Information

Publication Date 2008-10-01
DOI 10.1039/B814558J
Impact Factor 6.222
Authors

Sven Thorwirth, Jürgen Gauss, Michael C. McCarthy, François Shindo, Patrick Thaddeus


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Abstract

Unsubstituted silanethione, H2SiS, has been characterized experimentally for the first time by means of rotational spectroscopy; the equilibrium structure of this fundamental molecule has been evaluated through a combination of experimental data from a total of ten isotopologues and results of high-level coupled-cluster calculations.

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