Photochemical modification of diamond powders with elemental sulfur and their surface-attachment behavior on gold surfaces
Literature Information
Takako Nakamura, Tsuguyori Ohana, Yuta Hagiwara, Toshiki Tsubota
A useful method of modifying the surface of diamond powder with sulfur-containing functionalities was developed by the photolysis of elemental sulfur. The introduction of sulfur-containing functional groups on the diamond surfaces was confirmed by X-ray photoelectron spectroscopy (XPS), diffuse reflectance Fourier transform infrared spectroscopy (DRIFT) and mass spectroscopy analyses. The sulfur-modified diamond powder attached to gold surfaces through sulfur-containing linkages. In brief, the exposure of the modified diamond powder to a gold colloid resulted in gold nanoparticles being attached to the diamond powder. The treatment of the modified diamond powder with thin gold film on a Si substrate resulted in the alignment of surface-attached diamond powder through sulfur linkages formed by self-assembly.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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