Encapsulation of charge-diffuse peralkylated onium cations in the cavity of cucurbit[7]uril

Literature Information

Publication Date 2008-09-16
DOI 10.1039/B811823J
Impact Factor 6.222
Authors

Antony D. St-Jacques, Ian W. Wyman, Donal H. Macartney


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Abstract

Cucurbit[7]uril binds, with considerable size selectivity, NR4+, PR4+, and SR3+ cations (R = Me, Et, nPr, nBu), with the smaller guests inside its cavity, rather than at the carbonyl-lined portals.

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