Axial chirality control of troposBIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation‡

Literature Information

Publication Date 2008-09-30
DOI 10.1039/B809683J
Impact Factor 6.222
Authors

Kohsuke Aikawa, Yūki Takabayashi, Susumu Kawauchi, Koichi Mikami


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Abstract

Diastereopure troposRh complexes bearing not only BIPHEP but also chiral dienes can be employed as highly enantioselective hydrogenation catalysts for an olefinic substrate.

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