Coordination networks derived from germanium(ii) thioether macrocyclic complexes—the first authenticated chalcogenoether complexes of Ge(ii)

Literature Information

Publication Date 2008-09-22
DOI 10.1039/B809444F
Impact Factor 6.222
Authors

Fei Cheng, Andrew L. Hector, William Levason, Gillian Reid, Michael Webster, Wenjian Zhang


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Abstract

Exocyclic coordination of macrocyclic thioethers to germanium(II) halides leads to infinite chains (with weak Ge⋯X bridges between the chains) or sheet structures containing distorted octahedral Ge(II) with [S2X2 + X2] coordination and bridging thiacrowns.

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