Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state

Literature Information

Publication Date 2008-09-01
DOI 10.1039/B809136F
Impact Factor 6.222
Authors

Mangayarkarasi Nagarathinam, Abdul Malik Puthan Peedikakkal, Jagadese J. Vittal


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Abstract

trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a CC bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt’s postulates, are discussed.

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