Competition between planar and central chiral control elements in nucleophilic addition to ferrocenyl imine derivatives

Literature Information

Publication Date 2008-09-12
DOI 10.1039/B808045C
Impact Factor 6.222
Authors

Kévin M. Joly, Claire Wilson, Alexander J. Blake, James H. R. Tucker, Christopher J. Moody


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Abstract

Planar chirality associated with the ferrocene in ferrocenyl oximes and hydrazones bearing chiral auxiliaries effectively competes with or overrides the normally excellent stereocontrol afforded by the auxiliary in determining the diastereoselectivity of addition to the CN bond.

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