Ni(ii)-catalyzed enantioselective Nazarov cyclizations

Literature Information

Publication Date 2008-07-17
DOI 10.1039/B806870D
Impact Factor 6.222
Authors

Irene Walz, Antonio Togni


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Abstract

Nazarov cyclizations are catalyzed by a dicationic Ni(II) complex containing the chiral tridentate phosphine Pigiphos; the catalyst exerts a high degree of torquoselectivity and affords the products in up to 88% ee.

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