Reactivity of a Co(i) [N2P2] complex with azides: evidence for a transient Co(iii) imido species
Literature Information
Wayne A. Chomitz, John Arnold
The synthesis of a monomeric Co(I) complex supported by a multidentate monoanionic [N2P2] ligand is described; interaction with aryl azides at low temperature generates a species whose reactivity is consistent with imido (“CoNR”) character.
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