Reactivity of a Co(i) [N2P2] complex with azides: evidence for a transient Co(iii) imido species

Literature Information

Publication Date 2008-06-23
DOI 10.1039/B804754E
Impact Factor 6.222
Authors

Wayne A. Chomitz, John Arnold


View Original

Abstract

The synthesis of a monomeric Co(I) complex supported by a multidentate monoanionic [N2P2] ligand is described; interaction with aryl azides at low temperature generates a species whose reactivity is consistent with imido (“CoNR”) character.

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DOI: 10.1039/C4AN90089H

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