Reversible shrinkage and expansion of a blue photofluorescent cadmium coordination polymer and in situtetrazole ligand synthesis

Literature Information

Publication Date 2008-03-13
DOI 10.1039/B800938D
Impact Factor 6.222
Authors

Hong Deng, Yong-Cai Qiu, Ying-Hua Li, Zhi-Hui Liu, Rong-Hua Zeng, Matthias Zeller, Stuart R. Batten


View Original

Abstract

The metal–organic framework [Cd15(5MT)18(OH)4(SO4)4] (5-MT = 5-methyl-1H-tetrazole) with an unprecedented Cd3(μ3-OH)(μ3-SO4) core and two kinds of tetrazole coordination modes was formed by self-assembly and in situ synthesis of the 5-MT tetrazole ligand; the structure exhibits an unusual 39·412·515 topological network and shows reversible shrinkage and expansion in a crystal-to-crystal dehydration/rehydration process.

Related Literature

Microsecond folding experiments and simulations: a match is made

M. B. Prigozhin

2013-01-29 Perspective

DOI: 10.1039/C3CP43992E

Back cover

Cover

DOI: 10.1039/C3CP90033A

Alternating chirality in the monolayer H2TPP on Cu(110)–(2 × 1)O

Margareta Wagner, Peter Puschnig, Stephen Berkebile, Falko P. Netzer, Michael G. Ramsey

2013-02-07 Paper

DOI: 10.1039/C3CP44239J

Nuclear magnetic resonance predictions for graphenes: concentric finite models and extrapolation to large systems

Jarkko Vähäkangas, Suvi Ikäläinen, Perttu Lantto, Juha Vaara

2013-02-01 Paper

DOI: 10.1039/C3CP44631J

Impact of surface steps and oxygen pre-coverage on the adsorption of methylamine on gold

April D. Lewoczko, Joseph J. BelBruno

2013-02-11 Paper

DOI: 10.1039/C3CP44471F

Front cover

Cover

DOI: 10.1039/C3CP90031B

An investigation of the photophysical properties of minor groove bound and intercalated DAPI through quantum-mechanical and spectroscopic tools

Alessandro Biancardi, Tarita Biver, Fernando Secco, Benedetta Mennucci

2013-01-23 Paper

DOI: 10.1039/C3CP44058C

Bonding trends within ternary isocoordinate chalcogenide glasses GexAsySe1−x−y

George Opletal, Rong P. Wang, Salvy P. Russo

2013-02-13 Paper

DOI: 10.1039/C3CP43364A

STM imaging, spectroscopy and manipulation of a self-assembled PTCDI monolayer on epitaxial graphene

A. J. Mayne, G. Comtet, G. Dujardin, Y. Kuk, Ph. Sonnet, L. Stauffer, S. Nagarajan, A. Gourdon

2013-02-11 Paper

DOI: 10.1039/C3CP42591F

You might also like

Compound Q&A

How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?

Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...

100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A

How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?

7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...

1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A

What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?

2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...

124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A

Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?

1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...

1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A

What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?

The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...

113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A

What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?

3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...

163271-80-53-(Triisopropylsilyl...
Compound Q&A

What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?

6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...

81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A

How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?

Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...

885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A

What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?

N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...

55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A

What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?

6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...

1036756-15-66-Bromo-8-fluoro-2-q...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.