Anion–arene adducts: C–H hydrogen bonding, anion–π interaction, and carbon bonding motifs
Literature Information
Benjamin P. Hay, Vyacheslav S. Bryantsev
This article summarizes experimental and theoretical evidence for the existence of four distinct binding modes for complexes of anions with charge-neutral arenes. These include C–H hydrogen bonding and three motifs involving the arene–π system—the noncovalent anion–π interaction, weakly covalent σ interaction, and strongly covalent σ interaction.
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