N-Metalated imines by reaction of 1,1-diethoxybut-2-ene with aromatic nitriles, as useful intermediates for the synthesis of substituted pyrimidines and cyclopentenones‡

Literature Information

Publication Date 2008-02-07
DOI 10.1039/B719462E
Impact Factor 6.222
Authors

Marco Blangetti, Annamaria Deagostino, Cristina Prandi, Paolo Venturello


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Abstract

A new approach to the synthesis of pyrimidines and cyclopentenones is described. The method exploits the reactivity of α,β-unsaturated acetals with aromatic nitriles in the presence of the Schlosser’s superbase LIC-KOR.

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