Direct synthesis of the 1,2,3-[C6H4PPP]− anion, isoelectronic with the indenyl anion [C6H4CHCHCH]−

Literature Information

Publication Date 2008-01-15
DOI 10.1039/B718425E
Impact Factor 6.222
Authors

Felipe García, Robert J. Less, Vesal Naseri, Mary McPartlin, Jeremy M. Rawson, Maria Sancho Tomas, Dominic S. Wright


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Abstract

The two products obtained from the reaction of 1,2-(PH2)2C6H4 with the mixed-metal base nBuLi–Sb(NMe2)3 in the presence of 12-crown-4, [Li(12-crown-4)2]+[C6H4P3]− (1) and {[Li(12-crown-4)2]+}3[Sb11]3− (2), represent thermodynamic sinks in which P–P and Sb–Sb bonding are maximized at the expense of P–Sb bonding, providing access to the 1,2,3-[C6H4P3]− phospholide anion.

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