Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes

Literature Information

Publication Date 2008-01-04
DOI 10.1039/B717858A
Impact Factor 6.222
Authors

Qing-Zheng Yang, Daria Khvostichenko, John D. Atkinson, Roman Boulatov


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Abstract

In weakly coordinating solvents FeII meso-(N-methylimidazol-2-yl)porphine 1Fe exists as a stable dimer (Kd = 50 ± 30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.

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