![(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone structure](https://static.chemtradehub.com/structs/102/102271-49-8-cba7.webp "(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone structure")
(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone
CAS Number:
102271-49-8
Molecular Formula:
C19H26O3
An unusually stable octanuclear σ-mesityl-bridged µ4-oxo-copper(i) complex encapsulated by a pyrazolate-based compartmental ligand scaffold
Literature Information
Publication Date
2008-02-06
DOI
10.1039/B717571J
Impact Factor
6.222
Authors
Michael Stollenz, Christian Große, Franc Meyer
View Original
Abstract
A new compartmental pyrazole-derived chelating ligand, four equivalents of mesitylcopper and stoichiometric amounts of dioxygen lead to the formation of a remarkably stable organometallic framework that can be described as a heteroleptic O-centered cuprate anion [(MesCuI)4(µ4-O)]2− linked via σ-mesityl-bridges to two surrounding binuclear CuI-pyrazolate clamps.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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