Solid state structures and photophysical properties of (trimethylsilyl)methyl-substituted anthracenes and pyrenes

Literature Information

Publication Date 2008-02-27
DOI 10.1039/B716770A
Impact Factor 6.222
Authors

Masaki Shimizu, Hironori Tatsumi, Kenji Mochida, Tamejiro Hiyama


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Abstract

(Trimethylsilyl)methyl groups incorporated at 9- and 9,10-positions of anthracenes and at 1,3,6,8-positions of pyrenes were found to orient perpendicular to the aromatic frameworks in their crystals and induce red-shift of UV absorption and fluorescence spectra and enhancement of fluorescence quantum yields as compared with the parent hydrocarbons.

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