Metal-specific allosteric activation and deactivation of a diamine

Literature Information

Publication Date 2007-11-15
DOI 10.1039/B714256K
Impact Factor 6.222
Authors

Hayley J. Clayton, Lindsay P. Harding, John P. Irvine, John C. Jeffery, T. Riis-Johannessen, Andrew P. Laws, Craig R. Rice, Martina Whitehead


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Abstract

The reaction of a potentially tetradentate bis(pyridyl–thiazole) ligand with acetone is allosterically activated upon complexation with Cd(II) but deactivated by reaction with Cu(I), demonstrating metal-specific allosteric controlled reactivity.

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