Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR′)(μ-I)2]3(μ3-O) (CpRR′ = C5Me5, C5Me4H, C5H4SiMe3)
Literature Information
Publication Date
2007-11-13
DOI
10.1039/B714211K
Impact Factor
6.222
Authors
Christopher P. Larch, F. Geoffrey N. Cloke, Peter B. Hitchcock
View Original
Abstract
The reaction of UI3 and KCpRR′ (CpRR′ = pentamethylcyclopentadienyl, trimethylsilylcyclopentadienyl or tetramethylcyclopentadienyl) in diethyl ether results in the two-electron reduction of the solvent to form trimetallic, mixed valence uranium oxo species.
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Chemical Communications
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8.6
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4.7%
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2458
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Molecular Formula:
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CAS Number:
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Molecular Formula:
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