Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate
Literature Information
David R. Armstrong, William Clegg, Sophie H. Dale, Joaquín García-Álvarez, Ross W. Harrington, Eva Hevia, Gordon W. Honeyman, Alan R. Kennedy, Robert E. Mulvey, Charles T. O'Hara
In a new type of reactivity for sodium TMP-zincate [(TMEDA)NaZn(tBu)2(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-α-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).
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