Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry
Literature Information
Publication Date
2007-10-12
DOI
10.1039/B713913F
Impact Factor
6.222
Authors
Ben Conway, Eva Hevia, Joaquín García-Álvarez, David V. Graham, Alan R. Kennedy, Robert E. Mulvey
View Original
Abstract
Lithium TMP-aluminate “iBu3Al(TMP)Li” undergoes dismutation in THF solution to precipitate the tetraalkylaluminate [{Li·(THF)4}+{Al(iBu)4}–], but reacts kinetically as a TMP base towards N,N-diisopropylbenzamide to afford the crystalline ortho-aluminated species [(THF)3·Li{O(C)N(iPr)2(C6H4)}Al(iBu)3] and TMPH.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
5,10,15,20-tetrakis(4-boronic acid pinacol ester phenyl) porphyrin
CAS Number:
1332748-00-1
Molecular Formula:
C68H74B4N4O8
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