Rh-catalyzed P–P bond activation

Literature Information

Publication Date 2007-10-16
DOI 10.1039/B712972F
Impact Factor 6.222
Authors

Stephen J. Geier, Douglas W. Stephan


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Abstract

A Rh-catalyst derived from (NacNac)Rh(COE)(N2) effects the hydrogenation and silylation of P–P bonds to give secondary phosphines and silylphosphines, (Ph2PH) and (Ph2PSiRR′2) respectively; the latter process is shown to also involve the silylation of secondary phosphines.

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