Macropolyhedral boron-containing cluster chemistry. Novel intercluster linkages from the reaction of [Pt(cod)Cl2] and [PtMe2(PMe2Ph)2] with 6,6′-(B10H13)2O
Literature Information
Jonathan Bould, John D. Kennedy
6,6′-(B10H13)2O with [Pt(cod)Cl2] gives the [(B10H13OB10H11)Pt–{(B10H10OB10H12)]2− anion in which, uniquely, the units are held together by a B–O–B linkage in combination with a B–B linkage; with [PtMe2(PMe2Ph)2] it gives [(PMe2Ph)2PtB10H10–O,H–B10H11Pt(PMe2Ph)] in which, uniquely, the units are held together by an unsupported hydrogen-to-metal linkage as well as a B–O–B linkage.
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