Diastereoselective synthesis and spin-dependent photodecarbonylation of di(3-phenyl-2-pyrrolidinon-3-yl)ketones: synthesis of nonadjacent and adjacent stereogenic quaternary centers

Literature Information

Publication Date 2007-11-12
DOI 10.1039/B711786H
Impact Factor 6.222
Authors

Marino J. E. Resendiz, Arunkumar Natarajan, Miguel A. Garcia-Garibay


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Abstract

A diastereoselective procedure to obtain N-para-methoxybenzyl bis-α,α′-3-(3-phenyl-2-pyrrolidinone)yl substituted ketones with non-adjacent quaternary stereocenters, DL-2 and meso-3 was followed by a photoinduced, spin-dependent, and diastereoselective decarbonylation to give compounds DL-4 and meso-5, with adjacent all-carbon quaternary stereogenic centers.

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Back matter

Front/Back Matter

DOI: 10.1039/C2CP90175G

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