Insight into the structure of supported palladium catalysts during the total oxidation of methane

Literature Information

Publication Date 2007-10-12
DOI 10.1039/B710222D
Impact Factor 6.222
Authors

Jan-Dierk Grunwaldt, Niels van Vegten, Alfons Baiker


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Abstract

The combination of in situ X-ray absorption spectroscopy, X-ray diffraction and on-line catalytic data provided insight into the structure–performance relationship of a flame-made Pd/ZrO2 catalyst during the total oxidation of methane: upon heating, a sudden reduction accompanied by sintering of the Pd-particles, leads to a significantly lower catalytic activity and a hysteresis during cooling down.

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