β-Chlorovinylsilanes as masked alkynes in oligoyne assembly: synthesis of the first aryl-end-capped dodecayne
Literature Information
Publication Date
2007-08-23
DOI
10.1039/B707681A
Impact Factor
6.222
Authors
Simon M. E. Simpkins, Michael D. Weller, Liam R. Cox
View Original
Abstract
An aryl-end-capped dodecayne has been prepared using a four-fold fluoride-mediated dechlorosilylation of a masked dodecayne precursor containing four β-chlorovinylsilane residues that serve as masked alkynes; the unstable dodecayne product has been characterised by UV-vis absorption spectroscopy and ‘matrix-free’ MALDI-TOF mass spectrometry.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![4,4'-[2,5-Biphenyldiylbis(oxy)]dianiline structure](https://static.chemtradehub.com/structs/941/94148-67-1-24c6.webp "4,4'-[2,5-Biphenyldiylbis(oxy)]dianiline structure")
![2,2'-[(Abieta-8,11,13-trien-18-ylimino)bis(2,1-ethanediyloxy)]diethanol structure](https://static.chemtradehub.com/structs/513/51344-62-8-8518.webp "2,2'-[(Abieta-8,11,13-trien-18-ylimino)bis(2,1-ethanediyloxy)]diethanol structure")
2,2'-[(Abieta-8,11,13-trien-18-ylimino)bis(2,1-ethanediyloxy)]diethanol
CAS Number:
51344-62-8
Molecular Formula:
C28H47NO4
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