High pressure studies on molten zinc chloride
Literature Information
Gerhard Heusel, Helmut Bertagnolli, Markus Kreitmeir, Jörg Neuefeind, Andre Lemke
The structure of molten zinc chloride was investigated at pressures up to 3000 bar and temperatures up to 500 °C with a new high pressure cell. The distinct terms and the total atom pair correlation functions were determined with high energy photons. The distinct terms show systematic change in the low κ-range between 0 and 3 Å−1 as a function of the applied pressure. A reduction of the first sharp diffraction peak (prepeak) intensity of the distinct part is observed with increasing pressure. It is concluded, that this behaviour indicates a network breaking tendency of the corner shared [ZnCl4]2− tetrahedra with increasing pressure, while the tetrahedra themselves remain unchanged over the whole applied pressure and temperature range.
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