Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid
Literature Information
John E. Bercaw, Robert H. Grubbs, Nilay Hazari, Jay A. Labinger, Xingwei Li
The yield of triptane from the reaction of methanol with zinc iodide is dramatically increased by addition of phosphorous or hypophosphorous acid, via transfer of hydride from a P–H bond to carbocationic intermediates.
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Chemical Communications

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