Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid

Literature Information

Publication Date 2007-06-20
DOI 10.1039/B705470J
Impact Factor 6.222
Authors

John E. Bercaw, Robert H. Grubbs, Nilay Hazari, Jay A. Labinger, Xingwei Li


View Original

Abstract

The yield of triptane from the reaction of methanol with zinc iodide is dramatically increased by addition of phosphorous or hypophosphorous acid, via transfer of hydride from a P–H bond to carbocationic intermediates.

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Chemical Communications

Chemical Communications
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