Stereospecific aziridination of olefinsviaelectrophile-induced cyclization of γ,δ-unsaturated imines and subsequent hydrolytic rearrangement
Literature Information
Matthias D'hooghe, Mark Boelens, Johan Piqueur, Norbert De Kimpe
The olefinic bond of γ,δ-unsaturated aldehydes underwent a net aziridination through electrophile-induced cyclization and subsequent rearrangement of the resulting cyclic iminium salts: this methodology allows the stereospecific introduction of aziridine moieties into cyclic systems.
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