Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules‡

Literature Information

Publication Date 2007-04-18
DOI 10.1039/B701322A
Impact Factor 6.222
Authors

Toru Amaya, Koichi Mori, Hsyueh-Liang Wu, Satoshi Ishida, Jun-ichi Nakamura, Kazuhiko Murata, Toshikazu Hirao


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Abstract

A series of π-extended bowl-shaped π-conjugated compounds were synthesized from sumanene and characterized, and among them the terthiophene derivative showed a remarkable red-shifted absorption and small band gap, which was rationalized by molecular orbital calculation.

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