Nucleophilic aromatic substitution using Et3SiH/cat. t-Bu-P4 as a system for nucleophile activation

Literature Information

Publication Date 2007-02-28
DOI 10.1039/B700140A
Impact Factor 6.222
Authors

Masahiro Ueno, Misato Yonemoto, Masahiro Hashimoto, Andrew E. H. Wheatley, Hiroshi Naka, Yoshinori Kondo


View Original

Abstract

A novel type of deprotonative arylation of nucleophiles was conducted using Et3SiH/cat. t-Bu-P4 and the powerful SNAr reactions of aryl fluorides were accomplished using alcohols and malonates as nucleophiles.

Related Literature

First acid dissociation at an aqueous H2SO4 interface with sum frequency generation spectroscopy

Takayuki Miyamae, Yukio Ouchi

2008-02-19 Communication

DOI: 10.1039/B719496J

Electronic quenching of OH A 2Σ+ radicals in single collision events with H2 and D2: a comprehensive quantum state distribution of the OH X 2Π products

Logan P. Dempsey, Craig Murray, Patricia A. Cleary, Marsha I. Lester

2007-11-30 Paper

DOI: 10.1039/B715611A

Chiral signatures in angle-resolved valence photoelectron spectroscopy of pure glycidol enantiomers

Gustavo A. Garcia, Laurent Nahon, Chris J. Harding, Ivan Powis

2008-01-31 Paper

DOI: 10.1039/B714095A

Formation of a Criegee intermediate in the low-temperature oxidation of dimethyl sulfoxide

Rubik Asatryan, Joseph W. Bozzelli

2008-02-19 Paper

DOI: 10.1039/B716179D

Long-lasting dashed waves in a reactive microemulsion

Pablo Taboada, Victor Mosquera, Vladimir K. Vanag, Irving R. Epstein

2008-01-10 Communication

DOI: 10.1039/B714705H

Quantum mechanical limits to the control of atom–diatom chemical reactions through the polarisation of the reactants

Jesús Aldegunde, F. Javier Aoiz, Marcelo P. de Miranda

2007-12-21 Paper

DOI: 10.1039/B716482C

Inside front cover

Front/Back Matter

DOI: 10.1039/B802510J

Species with negative electron affinity and standard DFT methods. Finding the valence anions

Marcelo Puiatti, D. Mariano A. Vera, Adriana B. Pierini

2008-01-28 Communication

DOI: 10.1039/B716625G

Back cover

Front/Back Matter

DOI: 10.1039/B802979M

Back cover

Front/Back Matter

DOI: 10.1039/B803431C

You might also like

Compound Q&A

What regulatory guidelines apply to 4-Amino-3-bromophenol (CAS: 74440-80-5)?

4-Amino-3-bromophenol (CAS: 74440-80-5) falls under the classification of a haza...

74440-80-54-Amino-3-bromopheno...
Compound Q&A

How should (17beta)-3-Oxoestr-4-en-17-yl acetate (CAS: 1425-10-1) be stored?

(17beta)-3-Oxoestr-4-en-17-yl acetate should be stored in a cool, dry place away...

1425-10-1(17beta)-3-Oxoestr-4...
Compound Q&A

What are the physical and chemical properties of 2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0)?

2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0) is a colo...

76505-71-02-[(2,2-Diethoxyethy...
Compound Q&A

What is the market or research trend for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-amine?

The market and research for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-ami...

6736-58-91-(beta-D-Ribofurano...
Compound Q&A

How should waste containing Conjugated Estrogen (CAS: 12126-59-9) be handled?

Waste containing Conjugated Estrogen (CAS: 12126-59-9) should be collected and d...

12126-59-9Conjugated Estrogen
Compound Q&A

What is the market or research trend for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate?

The market for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate (CAS...

88738-78-7Bis(2,2,2-trifluoroe...
Compound Q&A

Are there alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9) in synthesis?

There are several alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9)...

57499-59-93,4'-Di-O-methylella...
Compound Q&A

What regulatory guidelines apply to 2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0)?

2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0) is regulated under the Gl...

59047-70-02-Chloro-N,N-dimethy...
Compound Q&A

What is cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8)?

Cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8) is a complex inorganic comp...

13597-19-8cerium(3+);oxygen(2-...
Compound Q&A

Is 7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) safe?

7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) is generally considered safe whe...

1203579-27-47-Chloro-1-iodoisoqu...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.