First acid dissociation at an aqueous H2SO4 interface with sum frequency generation spectroscopy

Literature Information

Publication Date 2008-02-19
DOI 10.1039/B719496J
Impact Factor 3.676
Authors

Takayuki Miyamae, Yukio Ouchi


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Abstract

The vibrational sum frequency generation (SFG) spectra of the air–liquid interface of H2SO4–H2O solutions over a wide range of concentrations are measured in the SO stretching region (1000–1300 cm−1). The analogy of the concentration dependence of Raman and SFG is indicative of a nearly identical behavior of the first acid dissociation at the air–liquid interface as in the bulk.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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