Organometallic molecular materials: self-assembly through hydrogen bonding of an organoplatinum network structure with zeolite-like topology

Literature Information

Publication Date 2007-01-29
DOI 10.1039/B617341A
Impact Factor 6.222
Authors

Fenbao Zhang, Michael C. Jennings, Richard J. Puddephatt


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Abstract

The complex [Pt(OH)2Me2(dpa)], dpa = di-2-pyridylamine, undergoes a remarkable form of self-assembly through hydrogen bonding in the solid state; there are cyclic tetramer units formed by head-to-head association between pairs of hydroxyl groups, and cyclic hexamer units formed by head-to-tail association between NH and OH groups; these building blocks then self-assemble to form a complex network structure containing large interconnected cavities, reminiscent of zeolites.

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