Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen
Literature Information
Shih-Ching Chuang, Michihisa Murata, Sadayuki Mori, Shuhei Maeda, Fumiyuki Tanabe
A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.
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