A new chiral diiron catalyst for enantioselective epoxidation
Literature Information
Caroline Marchi-Delapierre, Adeline Jorge-Robin, Aurore Thibon, Stéphane Ménage
The dinuclear chiral complex Fe2O(bisPB)4(X)2(ClO4)4 (X = H2O or CH3CN) catalyzes with high efficiency (up to 850 TON) and moderate enantioselectivity (63%) the epoxidation of electron deficient alkenes at 0 °C by a peracid.
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