A new chiral diiron catalyst for enantioselective epoxidation

Literature Information

Publication Date 2006-12-19
DOI 10.1039/B616172C
Impact Factor 6.222
Authors

Caroline Marchi-Delapierre, Adeline Jorge-Robin, Aurore Thibon, Stéphane Ménage


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Abstract

The dinuclear chiral complex Fe2O(bisPB)4(X)2(ClO4)4 (X = H2O or CH3CN) catalyzes with high efficiency (up to 850 TON) and moderate enantioselectivity (63%) the epoxidation of electron deficient alkenes at 0 °C by a peracid.

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