Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster
Literature Information
Daniele Belletti, Pierre Braunstein, Abdelatif Messaoudi, Giovanni Predieri, Antonio Tiripicchio
In the clusters [Ru3(μ3-NPPh3)(μ3-OSiMe3)(μ-X)(μC,O-OCNPPh3)(μ-CO)(CO)6] (X = NCO, 2; X = Cl, 3), which were prepared by a pyrolytic reaction of Ph3PNSiMe3 with Ru3(CO)12, the ligands result from a cluster-mediated pseudo-Hofmann rearrangement involving the μ-NCO, μ(C,O)-Ph3PN–CO and μ3-NPPh3 fragments.
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