First steps towards dissolution of NaSO4− by water
Literature Information
Barbara Jagoda-Cwiklik, Pavel Jungwirth
NaSO4−(H2O)n (n = 0–4) clusters have been generated in the gas phase as model systems to simulate the first dissolution steps of sulfate salts in water; photoelectron spectroscopy and theoretical calculations indicate that the first three water molecules strongly interact with both Na+ and SO42−, forming a three-water solvation ring to start to pry apart the Na+SO42− contact ion pair.
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