Biomimetic synthesis of marine sponge metabolite spiculoic acid A and establishment of the absolute configuration of the natural product
Literature Information
James E. D. Kirkham, Victor Lee, Jack E. Baldwin
The synthesis of spiculoic acid A (1) using a biomimetic Diels–Alder reaction is described; comparison of the specific rotation of the natural and synthetic material revealed that the enantiomer of the natural product has been synthesized.
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