High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons

Literature Information

Publication Date 2006-07-06
DOI 10.1039/B606736K
Impact Factor 6.222
Authors

David R. Allan, Alexander J. Blake, Deguang Huang, Timothy J. Prior, Martin Schröder


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Abstract

The mononuclear Pd(II) complex cis-[PdCl2([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.

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