Nickel catalyzed stereoselective conjugate addition of dimethylzinc upon aldimines across 1,3-dien-8-ynes and 1,3-dien-9-ynes

Literature Information

Publication Date 2006-05-31
DOI 10.1039/B605728D
Impact Factor 6.222
Authors

Masanari Kimura, Masahiko Mori, Nahoko Mukai, Keisuke Kojima, Yoshinao Tamaru


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Abstract

Ni(acac)2 catalyzes the five-component connection reaction of Me2Zn, alkynes, diene (of 1,3-dien-8-ynes and 1,3-dien-9-ynes), aldehydes and anisidine to furnish cyclic dienyl amines anti-2 with high remote 1,5-diastereoselectivity.

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