2,2′-Disubstituted F12binaphthyl derivatives: stannanes, boranes, and (R)-F12BINOL
Literature Information
Publication Date
2006-06-19
DOI
10.1039/B605716K
Impact Factor
6.222
Authors
Darryl J. Morrison, Susanne D. Riegel, Warren E. Piers, Masood Parvez, Robert McDonald
View Original
Abstract
2,2′-Distannyl derivatives of dodecafluorobinaphthalene are converted to a novel D2 symmetric borane dimer, which can be oxidized to (±)-F12BINOL; resolution using (S)-acetoxypropanoyl chloride affords enantiopure material.
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Source Journal
Chemical Communications
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