Notable norbornene (NBE) incorporation in ethylene–NBE copolymerization catalysed by nonbridged half-titanocenes: better correlation between NBE incorporation and coordination energy

Literature Information

Publication Date 2006-05-18
DOI 10.1039/B605005K
Impact Factor 6.222
Authors

Kotohiro Nomura, Wei Wang, Michiya Fujiki, Jingyu Liu


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Abstract

CpTiCl2(NCtBu2) exhibits both remarkable catalytic activity and efficient norbornene (NBE) incorporation for ethylene–NBE copolymerization: the NBE incorporation by Cp′TiCl2(X) (X = NCtBu2, O-2,6-iPr2C6H3; Cp′ = Cp, C5Me5, indenyl) was related to the calculated coordination energy after ethylene insertion.

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