Notable norbornene (NBE) incorporation in ethylene–NBE copolymerization catalysed by nonbridged half-titanocenes: better correlation between NBE incorporation and coordination energy
Literature Information
Kotohiro Nomura, Wei Wang, Michiya Fujiki, Jingyu Liu
CpTiCl2(NCtBu2) exhibits both remarkable catalytic activity and efficient norbornene (NBE) incorporation for ethylene–NBE copolymerization: the NBE incorporation by Cp′TiCl2(X) (X = NCtBu2, O-2,6-iPr2C6H3; Cp′ = Cp, C5Me5, indenyl) was related to the calculated coordination energy after ethylene insertion.
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