Selective aerobic oxidation in supercritical carbon dioxide catalyzed by the H5PV2Mo10O40 polyoxometalate

Literature Information

Publication Date 2006-04-25
DOI 10.1039/B603148J
Impact Factor 6.222
Authors

Galia Maayan, Benjamin Ganchegui, Ronny Neumann


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Abstract

Selective aerobic oxidation of benzylic alcohols and of activated aromatic hydrocarbons occurs in supercritical CO2 as reaction medium using H5PV2Mo10O40 as a quasi-heterogeneous catalyst without further additives or co-solvents; efficient recycling is possible and no metal leaching is detectable in the product stream.

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