Sandra J. Thompson, Nicola Goldberg, Bruce S. Ault
The thermal and photochemical reactions between CrO2Cl2 and H2S have been investigated using matrix isolation infrared spectroscopy. Twin-jet co-deposition of the two reagents into argon matrices at 14 K followed by irradiation with light of λ > 300 nm led to the growth of a number of new bands. These have been assigned to the HSOH–CrCl2O complex, and to SO2. These assignments were supported by deuterium isotopic substitution and high level density functional calculations. Merged-jet deposition with the reaction zone at temperatures above 125 °C led to substantial yields of SO2 and HCl, as well as the complex of HCl with excess parent H2S. The evidence suggests that the thermal and photochemical reactions may follow different pathways.
Karl-Heinz Dostert, Casey P. O'Brien, Francesca Mirabella, Francisco Ivars-Barceló
DOI: 10.1039/C6CP00877A
Baris Demir, Tiffany R. Walsh, Tom Welton
DOI: 10.1039/C6CP01216G
Edmund M. Mills, Matthias Kleine-Boymann, Juergen Janek, Hao Yang, Nigel D. Browning, Yayoi Takamura, Sangtae Kim
DOI: 10.1039/C5CP08032K
C. Awada, J. Plathier, C. Dab, F. Charra, L. Douillard, A. Ruediger
DOI: 10.1039/C5CP08015K
Weiguang Kong, Tao Ding, Gang Bi, Huizhen Wu
DOI: 10.1039/C6CP00325G
T. I. Hukka, T. T. Rantala
DOI: 10.1039/C6CP02510B
Huachun Lan, Huijuan Liu, Jiuhui Qu
DOI: 10.1039/C5CP07713C
Philippe Bühlmann, Thomas C. Allison
DOI: 10.1039/C6CP00393A
Chuanxun Su, Jurong Zhang, Guangtao Liu, Xin Wang, Hui Wang, Yanming Ma
DOI: 10.1039/C6CP01484D
Xiao Pan, Xuefei Feng, Chia-Hsin Wang, Yaw-Wen Yang
DOI: 10.1039/C5CP08066E
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure](https://static.chemtradehub.com/structs/612/61270-78-8-6b58.webp "Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure")
