[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

Literature Information

Publication Date 2019-10-07
DOI 10.1039/C9CC05924E
Impact Factor 6.222
Authors

Zhao-Rui Wen, Zong-Jie Guan, Ying Zhang, Yu-Mei Lin


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Abstract

We report the total structure determination of a covalently bonded nanocluster polymer [Au7Ag9(dppf)3(CF3CO2)7BF4]n (1). This features a one-dimensional linear chain, consisting of unique molecular building blocks, Au7Ag8(dppf)3(CF3CO2)7 clusters, which are linked together by Ag–O bonds rather than Au–Au interactions or bidentate organic bridges as previously reported.

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