Enantioselective allylation of ketones catalyzed by chiral In(iii)-PYBOX complexes
Literature Information
Mei-Ling Hong, Shun-Jun Ji, Yong-Chua Teo
In the presence of 20 mol% of chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with achiral ketones to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (54–95% ee), which constitutes the first example of enantioselective allylation of ketones catalyzed by the chiral In(III)-PYBOX complex.
Recommended Journals
Related Literature
Multifunctional underwater superoleophobic cellulose-based composite aerogel with oil/water separation, dye adsorption, and antibacterial activities
Zhen Zhang, Linyan Zhao, Lin Cui, DongMei Li, Xing Tian, Zhiyong Liu, Shenglin Liu
DOI: 10.1039/D3NJ05042D
Contradictory role of reactive oxygen species in dissolution-dependent activity of Pb-based anodes in acidic electrooxidation
Feilong Zhang
DOI: 10.1039/D3TA05548E
Novel helix-shape bis[1,2,4]triazolo[4,3-b:3′,4′-f][1,2,4,5]tetrazines: synthesis, optical and charge-transfer properties
Anna V. Korotina, Svetlana G. Tolshchina, Denis A. Gazizov, Alexander S. Steparuk, Nadezhda S. Demina, Ilya N. Ganebnykh, Pavel A. Slepukhin, Alexey E. Aleksandrov, Alexey R. Tameev, Gennady L. Rusinov
DOI: 10.1039/D3NJ05306G
Organophotoredox-catalyzed stereoselective reductive dimerization of chromone-2-carboxylic esters
Tanaya Manna, Subhas Chandra Debnath, Syed Masood Husain
DOI: 10.1039/D3NJ05659G
Microporous organic nanoparticles bearing tri-Zn macrocycles: heterogeneous catalysts for the conversion of biomass-derived furan esters to polymer platforms
June Young Jang, Gang Min Lee, Jong Doo Lee, Seung Uk Son
DOI: 10.1039/D3TA04797K
Recent progress in polymer nanosheets for photocatalysis
Lei Wang, Jianyong Yue, Rong Wu, Zebo Fang, Yuxi Xu
DOI: 10.1039/D3TA05435G
Cathode interface materials based on perylene-diimide derivatives for thickness insensitivity and high fill factor heterojunction organic solar cells
Lei Li, Jie Xu, Wenli Luo, Ke Zhong, Xiaohong Zhao, Yu Hu, Zhongyi Yuan, Yiwang Chen
DOI: 10.1039/D3TA04833K
Defect engineering: the role of cationic vacancies in photocatalysis and electrocatalysis
Wenming Ding, Shengbo Yuan, Yang Yang, Xiaoman Li, Min Luo
DOI: 10.1039/D3TA04947G
A phenylboronic acid-based smart photonic crystal hydrogel sensor for colorimetric detection of glucose
Jingya Wen, Xi Wang
DOI: 10.1039/D3NJ04656G
Sulfonate compounds embraced from acid copper electroplating baths as innovative additives for alkaline Zn batteries
Katerina Bogomolov, Ekaterina Grishina
DOI: 10.1039/D3TA04612E
You might also like
How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?
Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...
How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?
N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...
What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?
The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...
How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?
Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...
What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?
2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...
What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?
1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...
Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?
Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...
What precautions should be taken when handling 1-((2R,3R,4R,5R)-5-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxy-3-methoxytetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione (CAS: 153631-19-7)?
Proper personal protective equipment (PPE) must be worn when handling this compo...
What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?
When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...
Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?
Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














![[5-fluoro-2-(morpholine-4-carbonyl)phenyl]boronic acid structure [5-fluoro-2-(morpholine-4-carbonyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/121/1217501-26-2-505c.webp)