Enantioselective allylation of ketones catalyzed by chiral In(iii)-PYBOX complexes

Literature Information

Publication Date 2005-07-25
DOI 10.1039/B507768K
Impact Factor 6.222
Authors

Mei-Ling Hong, Shun-Jun Ji, Yong-Chua Teo


View Original

Abstract

In the presence of 20 mol% of chiral catalytic complex prepared from In(OTf)3 and chiral PYBOX, allyltributylstannane reacted with achiral ketones to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (54–95% ee), which constitutes the first example of enantioselective allylation of ketones catalyzed by the chiral In(III)-PYBOX complex.

Related Literature

Multifunctional underwater superoleophobic cellulose-based composite aerogel with oil/water separation, dye adsorption, and antibacterial activities

Zhen Zhang, Linyan Zhao, Lin Cui, DongMei Li, Xing Tian, Zhiyong Liu, Shenglin Liu

2023-12-15 Paper

DOI: 10.1039/D3NJ05042D

Novel helix-shape bis[1,2,4]triazolo[4,3-b:3′,4′-f][1,2,4,5]tetrazines: synthesis, optical and charge-transfer properties

Anna V. Korotina, Svetlana G. Tolshchina, Denis A. Gazizov, Alexander S. Steparuk, Nadezhda S. Demina, Ilya N. Ganebnykh, Pavel A. Slepukhin, Alexey E. Aleksandrov, Alexey R. Tameev, Gennady L. Rusinov

2023-12-27 Paper

DOI: 10.1039/D3NJ05306G

Organophotoredox-catalyzed stereoselective reductive dimerization of chromone-2-carboxylic esters

Tanaya Manna, Subhas Chandra Debnath, Syed Masood Husain

2024-01-09 Communication

DOI: 10.1039/D3NJ05659G

Microporous organic nanoparticles bearing tri-Zn macrocycles: heterogeneous catalysts for the conversion of biomass-derived furan esters to polymer platforms

June Young Jang, Gang Min Lee, Jong Doo Lee, Seung Uk Son

2023-10-20 Communication

DOI: 10.1039/D3TA04797K

Recent progress in polymer nanosheets for photocatalysis

Lei Wang, Jianyong Yue, Rong Wu, Zebo Fang, Yuxi Xu

2023-10-16 Review Article

DOI: 10.1039/D3TA05435G

Cathode interface materials based on perylene-diimide derivatives for thickness insensitivity and high fill factor heterojunction organic solar cells

Lei Li, Jie Xu, Wenli Luo, Ke Zhong, Xiaohong Zhao, Yu Hu, Zhongyi Yuan, Yiwang Chen

2023-10-18 Paper

DOI: 10.1039/D3TA04833K

Defect engineering: the role of cationic vacancies in photocatalysis and electrocatalysis

Wenming Ding, Shengbo Yuan, Yang Yang, Xiaoman Li, Min Luo

2023-10-17 Review Article

DOI: 10.1039/D3TA04947G

Sulfonate compounds embraced from acid copper electroplating baths as innovative additives for alkaline Zn batteries

Katerina Bogomolov, Ekaterina Grishina

2023-10-18 Paper

DOI: 10.1039/D3TA04612E

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.