Defect engineering: the role of cationic vacancies in photocatalysis and electrocatalysis

Literature Information

Publication Date 2023-10-17
DOI 10.1039/D3TA04947G
Impact Factor 12.732
Authors

Wenming Ding, Shengbo Yuan, Yang Yang, Xiaoman Li, Min Luo


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Abstract

Defect engineering is an effective strategy for regulating and controlling the properties of photocatalysts and electrocatalysts. Creating specific catalytic centers allows precise modulation of their electronic and material characteristics, enhancing electron enrichment. Defects generate synergistic unsaturated sites as active catalytic sites for chemisorption and activation in catalysis. This article systematically discusses the role of cationic vacancies in defect engineering, covering aspects such as synthesis methods, testing techniques and applications. It comprehensively summarizes recent research, underscoring applications in hydrogen evolution reactions (HER), oxygen evolution reaction (OER), CO2 reduction reactions (CO2RR) and nitrogen reduction reactions (NRR). In particular, the key role of cationic vacancy defect strategies in various applications is highlighted. Finally, the future opportunities, challenges, and prospects for further development of cation-defect-engineered catalysts are anticipated. The objective of this report is to elucidate the nature of cationic vacancy catalysts and provide valuable insights for designing defective cationic catalysts for various catalytic reactions.

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Source Journal

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
Self-citation Rate: 4.7%
Articles per Year: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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