Photochemical release of nitric oxide from a regenerable, sol-gel encapsulated Ru–salen–nitrosyl complex

Literature Information

Publication Date 2005-07-25
DOI 10.1039/B507407J
Impact Factor 6.222
Authors

Jeane Bordini, Peter C. Ford, Elia Tfouni


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Abstract

Light actviation leads to release of NO from a silicate sol-gel material SG-RuNO prepared from the ruthenium complex, [Ru(salen)(OH2)(NO)]+ (salen = N,N′-bis-(salicylidene)ethyl-enediaminato); after photochemical NO photolabilization, SG-RuNO can be regenerated from the spent material via the subsequent reaction with aqueous nitrite.

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