Structural and EPR characterisation of single electron and alkyl transfer products from reaction of dimethyl magnesium with bulky α-diimine ligands‡

Literature Information

Publication Date 2005-08-17
DOI 10.1039/B505697G
Impact Factor 6.222
Authors

Philip J. Bailey, Robert A. Coxall, Caroline M. Dick, Sylvie Fabre, Simon Parsons, Lesley J. Yellowlees


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Abstract

Treatment of dimethylmagnesium with bulky α-diimine ligands provides either the biradical methyl-bridged complexes [(α-diimine−˙)Mg+(μ-CH3)]2via single electron transfer (SET), or the product of methyl transfer to an imine carbon atom depending upon conditions.

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