Structural and EPR characterisation of single electron and alkyl transfer products from reaction of dimethyl magnesium with bulky α-diimine ligands‡
Literature Information
Philip J. Bailey, Robert A. Coxall, Caroline M. Dick, Sylvie Fabre, Simon Parsons, Lesley J. Yellowlees
Treatment of dimethylmagnesium with bulky α-diimine ligands provides either the biradical methyl-bridged complexes [(α-diimine−˙)Mg+(μ-CH3)]2via single electron transfer (SET), or the product of methyl transfer to an imine carbon atom depending upon conditions.
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![N-[(5,6-Dichloro-1H-benzimidazol-2-yl)methyl]-9-(1-methyl-1H-pyrazol-4-yl)-2-(4-morpholinyl)-9H-purin-6-amine structure N-[(5,6-Dichloro-1H-benzimidazol-2-yl)methyl]-9-(1-methyl-1H-pyrazol-4-yl)-2-(4-morpholinyl)-9H-purin-6-amine structure](https://static.chemtradehub.com/structs/238/2387704-62-1-25f4.webp)

